N,N-diallyl-p-toluenesulfonamide (5) was cycloisomerized in [D8]toluene (0.17 m) at 50 °C in the presence of B (5 mol%) and 2b (1 equiv). The relative contents of B, G and decomposition products were estimated by 31P NMR spectroscopy with H3PO4 (85%) as external standard and 1,2;5,6-dibenzanthracene (5 mol%) as internal standard.