2-Pyridyldiphenylphosphine, also known as Diphenyl-2-pyridylphosphine, is a tertiary phosphine ligand featuring a phosphorus atom bonded to two phenyl groups and one 2-pyridyl group. This hybrid structure combines both soft (phosphorus) and hard (nitrogen) donor atoms, making it a versatile chelating ligand in coordination chemistry and homogeneous catalysis. Its ability to bridge metal centers or coordinate through both phosphorus and nitrogen allows it to stabilize a range of metal complexes, particularly in catalytic systems such as hydrogenation, hydroformylation, and cross-coupling reactions. The electron-donating properties and steric bulk of the phenyl groups, combined with the coordination flexibility of the pyridyl ring, contribute to its popularity in organometallic and inorganic chemistry.
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We synthesized six mixed-ligand CuI complexes of the [Cu(N,O)(P,P)](BF4) type, where N,O is diphenyl(2-pyridyl)phosphine oxide (L1), diphenyl(8-quinolyl)phosphine oxide (L2) or diphenyl(2-pyridylmethyl)phosphine oxide (L3), and P,P is DPEphos or a pair of PPh3 ligands. The complex structures are shown in Scheme 1.
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