Saxitoxin is an alkaloid isolated from the marine dinoflagellates and cyanobacteria that causes paralytic shellfish poisoning. It has a role as a neurotoxin, a toxin, a sodium channel blocker, a marine metabolite and a cyanotoxin. It is a carbamate ester, a member of guanidines, an alkaloid, a pyrrolopurine, a ketone hydrate and a paralytic shellfish toxin. It is a conjugate base of a saxitoxin(2+).
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The novel transformation of a gem-CBr2 group to enol acetate followed by reduction, employed in the total synthesis of an analogue of saxitoxin.
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