Diazomethane, a yellow gas normally used as a solution in ether, readily esterifies fatty acids in the presence of methanol at room temperature. It is a strong respiratory irritant. Diazomethane is usually prepared by the decomposition of various derivatives of N-methyl-N-nitrosoamines.
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Quantum chemically computed Gibbs free-energy pathway for the cyclopropanation of DVTMS by diazomethane.
Quantum chemically computed lowest Gibbs free-energy pathway for the palladium(0)-catalyzed cy-clopropanation of trimethylvinylsilane by diazomethane.
Cycle for the palladium-catalyzed cyclopropanation of DVTMS by diazomethane according to experimental observations and DFT calculations.
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