Tetramethylammonium perchlorate
CAS number: 2537-36-2
Tetramethylammonium perchlorate (TMAP) consists of a tetramethylammonium cation and a perchlorate anion. It's a white crystalline solid, highly soluble in polar solvents like water and methanol. TMAP is used as an intermediate in organic and chemical synthesis, as a mobile phase in high performance liquid chromatography, and as a supporting electrolyte in electrochemistry.
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Plots of observed rate of pseudo-first-order decay, kobs, versus concentration of tetrabutylammonium acetate for deprotonation of the radical cations of (open circles) N,N-dimethylaniline, 1c, and N,N,-dimethylaniline with (filled circles) a 4-methyl substituent, 1b, (filled squares) a 2-methyl substituent, 2, and (open squares) a 2-tert-butyl substituent, 3, in acetonitrile with 0.5 m water and 0.5 m tetramethylammonium perchlorate, at room temperature.
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