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Tetrabutylammonium Acetate
CAS number: 10534-59-5
Tetrabutylammonium acetate is an organic salt used as a catalyst, curing agent, and initiator in polymer synthesis, and as a phase-transfer catalyst. It is also utilized in the preparation of ionic liquids and in analytical chemistry. It is a white to off-white solid, highly hygroscopic, and can be used in organic synthesis, electrochemistry, and biotechnology applications.

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Spectral, Kinetic, and Thermodynamic Properties Related to Deprotonation of Aromatic Amine Radical Cations with Tetrabutylammonium Acetate as the Base in Acetonitrile Containing 0.5 m Water and 0.5 m Tetrabutylammonium Perchlorate
Spectral, Kinetic, and Thermodynamic Properties Related to Deprotonation of Aromatic Amine Radical Cations with Tetrabutylammonium Acetate as the Base in Acetonitrile Containing 0.5 m Water and 0.5 m Tetrabutylammonium Perchlorate
DOI: /10.1021/jo047813g
Plots of observed rate of pseudo-first-order decay, kobs, versus concentration of tetrabutylammonium acetate for deprotonation of the radical cations of (open circles) N,N-dimethylaniline, 1c, and N,N,-dimethylaniline with (filled circles) a 4-methyl substituent, 1b, (filled squares) a 2-methyl substituent, 2, and (open squares) a 2-tert-butyl substituent, 3, in acetonitrile with 0.5 m water and 0.5 m tetramethylammonium perchlorate, at room temperature.
Plots of observed rate of pseudo-first-order decay, kobs, versus concentration of tetrabutylammonium acetate for deprotonation of the radical cations of (open circles) N,N-dimethylaniline, 1c, and N,N,-dimethylaniline with (filled circles) a 4-methyl substituent, 1b, (filled squares) a 2-methyl substituent, 2, and (open squares) a 2-tert-butyl substituent, 3, in acetonitrile with 0.5 m water and 0.5 m tetramethylammonium perchlorate, at room temperature.
DOI: /10.1021/jo047813g

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